Explore open access research and scholarly works from NERC Open Research Archive

Advanced Search

Subduction and melting of biogenic and ferromanganese sediments as evidenced by sub-Moho granitoids

Angelo, Tiago Valim; Spencer, Christopher J.; Li, Hong-Yan; Knaack, Derek; Zhu, Ziyi; Seraine, Marina; Roberts, Nick M.W.; Leduc, Evelyne; Divilek, Sophie; Ren, Anna; Joy, Brian; Lu, Gui-Mei. 2025 Subduction and melting of biogenic and ferromanganese sediments as evidenced by sub-Moho granitoids. Chemical Geology, 683, 122759. 10.1016/j.chemgeo.2025.122759

Abstract
Mantle-hosted granitoids (MHG) from the supra-subduction Samail ophiolite in Oman and the United Arab Emirates exhibit diverse compositions, highlighting variations in petrogenesis and source contributions. Previous isotopic data indicate these MHG originated through the interaction of sediment-derived with basaltic melts from an underthrust oceanic plate within the mantle wedge. The sedimentary contribution was attributed to the partial melting of pelitic to siliceous (bio-siliceous) material atop the subducted plate based on elevated zircon δ18O values (∼14–28 ‰). To further evaluate this hypothesis on Samail MHG petrogenesis and source contribution, we present new and compiled radiogenic (Sr-Nd-Hf-Pb) and stable (O-Li-H) isotopes, along with zircon trace element analyses. The variable Sr and Pb isotopic signature support a mixed origin involving altered mafic and sedimentary sources in the formation of the MHG. Negative whole-rock εNd, coupled with elevated δ7Li in muscovite suggest the involvement of sedimentary sources and particularly those resembling deep-sea ferromanganese-rich sediments. We propose a new model identifying ferromanganese sediments as a potential source given their widespread distribution across the ocean floor, broad range of δ18O (up to 29.5 ‰), slightly positive Hf values, seawater-like δ7Li signatures (median of ∼27 ‰), and zircon trace element compositions lacking a signature of monazite co-precipitation, which match the signatures required for the genesis of the Samail MHG. Preservation of oceanic lithosphere in the geological record is limited, and MHG in ophiolites are uncommon. Therefore, the Samail MHG are key examples of crustal materials transported to the mantle, with implications for mantle heterogeneity and arc mantle redox budget.
Documents
539445:261690
[thumbnail of Open Access Paper]
Preview
Open Access Paper
1-s2.0-S0009254125001494-main.pdf - Published Version
Available under License Creative Commons Attribution 4.0.

Download (10MB) | Preview
Information
Programmes:
BGS Programmes 2020 > Decarbonisation & resource management
Library
Statistics

Downloads per month over past year

More statistics for this item...

Metrics

Altmetric Badge

Dimensions Badge

Share
Add to AnyAdd to TwitterAdd to FacebookAdd to LinkedinAdd to PinterestAdd to Email
View Item