Multi-model study of mercury dispersion in the atmosphere: vertical and interhemispheric distribution of mercury species

Bieser, Johannes; Slemr, Franz; Ambrose, Jesse; Brenninkmeijer, Carl; Brooks, Steve; Dastoor, Ashu; DeSimone, Francesco; Ebinghaus, Ralf; Gencarelli, Christian N.; Geyer, Beate; Gratz, Lynne E.; Hedgecock, Ian M.; Jaffe, Daniel; Kelley, Paul; Lin, Che-Jen; Jaegle, Lyatt; Matthias, Volker; Ryjkov, Andrei; Selin, Noelle E.; Song, Shaojie; Travnikov, Oleg; Weigelt, Andreas; Luke, Winston; Ren, Xinrong; Zahn, Andreas; Yang, Xin ORCID: https://orcid.org/0000-0002-3838-9758; Zhu, Yun; Pirrone, Nicola. 2017 Multi-model study of mercury dispersion in the atmosphere: vertical and interhemispheric distribution of mercury species. Atmospheric Chemistry and Physics, 17 (11). 6925-6955. https://doi.org/10.5194/acp-17-6925-2017

Before downloading, please read NORA policies.

Preview

Text
Bieser.pdf - Published Version
Available under License Creative Commons Attribution.
Download (16MB) | Preview

Official URL: https://doi.org/10.5194/acp-17-6925-2017

Abstract/Summary

Atmospheric chemistry and transport of mercury play a key role in the global mercury cycle. However, there are still considerable knowledge gaps concerning the fate of mercury in the atmosphere. This is the second part of a model intercomparison study investigating the impact of atmospheric chemistry and emissions on mercury in the atmosphere. While the first study focused on ground-based observations of mercury concentration and deposition, here we investigate the vertical and interhemispheric distribution and speciation of mercury from the planetary boundary layer to the lower stratosphere. So far, there have been few model studies investigating the vertical distribution of mercury, mostly focusing on single aircraft campaigns. Here, we present a first comprehensive analysis based on various aircraft observations in Europe, North America, and on intercontinental flights. The investigated models proved to be able to reproduce the distribution of total and elemental mercury concentrations in the troposphere including interhemispheric trends. One key aspect of the study is the investigation of mercury oxidation in the troposphere. We found that different chemistry schemes were better at reproducing observed oxidized mercury patterns depending on altitude. High concentrations of oxidized mercury in the upper troposphere could be reproduced with oxidation by bromine while elevated concentrations in the lower troposphere were better reproduced by OH and ozone chemistry. However, the results were not always conclusive as the physical and chemical parameterizations in the chemistry transport models also proved to have a substantial impact on model results.

Item Type:	Publication - Article
Digital Object Identifier (DOI):	https://doi.org/10.5194/acp-17-6925-2017
Programmes:	BAS Programmes > BAS Programmes 2015 > Atmosphere, Ice and Climate
ISSN:	1680-7324
NORA Subject Terms:	Atmospheric Sciences Chemistry
Date made live:	27 Jun 2017 08:33 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/517227

Item Type:

Publication - Article

Digital Object Identifier (DOI):

https://doi.org/10.5194/acp-17-6925-2017

Programmes:

BAS Programmes > BAS Programmes 2015 > Atmosphere, Ice and Climate

ISSN:

1680-7324

NORA Subject Terms:

Atmospheric Sciences
Chemistry

Date made live:

27 Jun 2017 08:33 +0 (UTC)