Detrital zircon U-Pb and Hf constraints on provenance and timing of deposition of the Mesoproterozoic to Cambrian sedimentary cover of the East European Craton, part II: Ukraine

We present the U-Pb geochronology and Hf isotope analysis of detrital zircons from the Ediacaran/Cambrian sediments of Podillya and south Volyn in western Ukraine, supplemented by the bulk rock XRD mineralogy of the host rocks. Such a combined analytical approach allows for identifying the source areas supplying detritus to sediments and for constraining an age of deposition. Our provenance analysis is based on fourteen samples collected from six exposures, mostly in the valley of the Dniester river. 84 mudstone samples were also examined by the XRD method. U-Pb dating of detrital zircons yielded two sets of maximum depositional ages: 578–546 Ma and 547–523 Ma, for the Mohyliv-Podilsky and Kanyliv Series, respectively. This suggests that the Ediacaran-Cambrian boundary in Podillya coincides with a major erosional gap, with a major change in provenance, and the disappearance of the Ediacaran fauna at the base of the Kanyliv Series, with implications for the stratigraphy and paleogeography of the entire East European Platform. Zircon U-Pb age spectra from the lower part of the Mohyliv-Podilsky Series include a large quantity of 2.2 to 1.9 Ga grains that reveal predominantly negative to nearly chondritic ɛHf values, jointly suggesting detritus supply from the crystalline basement of Sarmatia. Both U-Pb and mineralogical data also indicate a major contribution of volcanic detritus from the Volyn flood basalts. The younger Nagoryany rocks yielded zircon age spectra with peaks at c. 1.80 and 1.49 Ga, implying a shift of the catchment area to Fennoscandia. Above an erosional gap, the zircon age spectra in the Kanyliv and Baltic Series are dominated by peaks at 560–535 Ma. These data and ɛHf values ranging from negative to chondritic and juvenile suggest, in line with the mineralogical data, detritus supply from a continental magmatic arc and collisional orogen. Thus, we interpret the Kanyliv Series as infill of an early Cambrian foreland basin that was established in front of the Scythides and Santacrucides orogens, overriding the SW margin of Baltica.