Evidence for fracture-hosted fluid-rock reactions within geothermal reservoirs of the eastern trans-Mexico volcanic belt

Fractures within hydrothermal systems represent major pathways for fluid flow, and it is therefore vital that we understand processes occurring along them as these may have an impact on productivity of hot fluids during geothermal exploitation. This is especially important where hydrothermal activity crosses contrasting rock types, as fluid movement can result in a range of fluid�rock reactions, mineral dissolution and precipitation, and possible changes in fracture permeability. Here we report evidence of fluid-rock reactions within basement carbonates and overlying volcanic rocks within hydrothermally altered rocks of the eastern trans-Mexico volcanic belt, as part of the Europe-Mexico collaborative ‘GEMex’ project (EU-H2020, GA No. 727550). Identified reactions within basement carbonates include initial high temperature Si-metasomatism linked to igneous intrusions to form minerals such as olivine, wollastonite, garnet and diopside, followed by subsequent lower temperature hydration (back reaction) at lower temperatures, where olivine and diopside hydrate to form serpentine and talc. Reactions of overlying andesitic units include Ca-metasomatism and bleaching through interaction of rising acidic, carbonate-equilibrated fluids. Secondary minerals produced during these reactions appear to seal fractures, implying tectonic reactivation of fractures to maintain long-term fluid flow through fracture zones.