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Segmented flow coil equilibrator coupled to a proton transfer reaction mass spectrometer for measurements of a broad range of volatile organic compounds in seawater

Wohl, Charel; Capelle, David; Jones, Anna ORCID: https://orcid.org/0000-0002-2040-4841; Sturges, William T.; Nightingale, Phillip D.; Else, Brent G.T.; Yang, Mingxi. 2019 Segmented flow coil equilibrator coupled to a proton transfer reaction mass spectrometer for measurements of a broad range of volatile organic compounds in seawater. Ocean Science, 15 (4). 925-940. 10.5194/os-15-925-2019

Abstract

We present a technique that utilises a segmented
flow coil equilibrator coupled to a proton-transferreaction
mass spectrometer to measure a broad range of dissolved
volatile organic compounds. Thanks to its relatively
large surface area for gas exchange, small internal volume,
and smooth headspace–water separation, the equilibrator is
highly efficient for gas exchange and has a fast response time
(under 1 min). The system allows for both continuous and
discrete measurements of volatile organic compounds in seawater
due to its low sample water flow (100 cm3 min

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Programmes:
BAS Programmes 2015 > Atmosphere, Ice and Climate
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