Deep urban groundwater vulnerability in India revealed through the use of emerging organic contaminants and residence time tracers

Lapworth, D.J. ORCID: https://orcid.org/0000-0001-7838-7960; Das, P.; Shaw, A.; Mukherjee, A.; Civil, W.; Petersen, J.O.; Gooddy, D.C.; Wakefield, O.; Finlayson, A.; Krishan, G.; Sengupta, P.; MacDonald, A.M. ORCID: https://orcid.org/0000-0001-6636-1499. 2018 Deep urban groundwater vulnerability in India revealed through the use of emerging organic contaminants and residence time tracers. Environmental Pollution, 240. 938-949. 10.1016/j.envpol.2018.04.053

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Abstract/Summary

Demand for groundwater in urban centres across Asia continues to rise with ever deeper wells being drilled to avoid shallow contamination. The vulnerability of deep alluvial aquifers to contaminant migration is assessed in the ancient city of Varanasi, India, using a novel combination of emerging organic contaminants (EOCs) and groundwater residence time tracers (CFC and SF6). Both shallow and intermediate depth private sources (<100 m) and deep (>100 m) municipal groundwater supplies were found to be contaminated with a range of EOCs including pharmaceuticals (e.g. sulfamethoxazole, 77% detection frequency, range <0.0001-0.034 µg L-1), perfluoroalkyl substances (e.g. PFOS, range <0.0001-0.033 µg L-1) as well as a number of pesticides (e.g. phenoxyacetic acid, range <0.02-0.21 µg L-1). The profile of EOCs found in groundwater mirror those found in surface waters, albeit at lower concentrations, and reflect common waste water sources with attenuation in the subsurface. Mean groundwater residence times were found to be comparable between some deep groundwater and shallow groundwater sources with residence times ranging from >70 to 30 years. Local variations in aquifer geology influence the extent of modern recharge at depth. Both tracers provide compelling evidence of significant inputs of younger groundwater to depth > 100 m within the aquifer system.

Item Type:	Publication - Article
Digital Object Identifier (DOI):	10.1016/j.envpol.2018.04.053
ISSN:	0269-7491
Additional Keywords:	GroundwaterBGS, Groundwater, International development, Groundwater quality, EOC
Date made live:	25 Jun 2018 13:29 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/520312

Item Type:

Publication - Article

Digital Object Identifier (DOI):

10.1016/j.envpol.2018.04.053

ISSN:

0269-7491

Additional Keywords:

GroundwaterBGS, Groundwater, International development, Groundwater quality, EOC

Date made live:

25 Jun 2018 13:29 +0 (UTC)

URI:

https://nora.nerc.ac.uk/id/eprint/520312