Fate and transport of polychlorinated biphenyls (PCBs) in the River Thames catchment – insights from a coupled multimedia fate and hydrobiogeochemical transport model

Lu, Q.; Futter, M.N.; Nizzeto, L.; Bussi, G.; Juergens, M.D. ORCID: https://orcid.org/0000-0002-6526-589X; Whitehead, P.G.. 2016 Fate and transport of polychlorinated biphenyls (PCBs) in the River Thames catchment – insights from a coupled multimedia fate and hydrobiogeochemical transport model. Science of the Total Environment, 572. 1461-1470. 10.1016/j.scitotenv.2016.03.029

Before downloading, please read NORA policies.

Preview

Text
N513112PP.pdf - Accepted Version
Available under License Creative Commons Attribution Non-commercial No Derivatives 4.0.
Download (1MB) | Preview

Official URL: http://dx.doi.org/10.1016/j.scitotenv.2016.03.029

Abstract/Summary

The fate of persistent organic pollutants (POPs) in riverine environments is strongly influenced by hydrology (including flooding) and fluxes of sediments and organic carbon. Coupling multimedia fate models (MMFMs) and hydrobiogeochemical transport models offers unique opportunities for understanding the environmental behaviour of POPs. While MMFMs are widely used for simulating the fate and transport of legacy and emerging pollutants, they use greatly simplified representations of climate, hydrology and biogeochemical processes. Using additional information about weather, river flows and water chemistry in hydrobiogeochemical transport models can lead to new insights about POP behaviour in rivers. As most riverine POPs are associated with suspended sediments (SS) or dissolved organic carbon (DOC), coupled models simulating SS and DOC can provide additional insights about POPs behaviour. Coupled simulations of river flow, DOC, SS and POP dynamics offer the possibility of improved predictions of contaminant fate and fluxes by leveraging the additional information in routine water quality time series. Here, we present an application of a daily time step dynamic coupled multimedia fate and hydrobiogeochemical transport model (The Integrated Catchment (INCA) Contaminants model) to simulate the behaviour of selected PCB congeners in the River Thames (UK). This is a follow-up to an earlier study where a Level III fugacity model was used to simulate PCB behaviour in the Thames. While coupled models are more complex to apply, we show that they can lead to much better representation of POPs dynamics. The present study shows the importance of accurate sediment and organic carbon simulations to successfully predict riverine PCB transport. Furthermore, it demonstrates the important impact of short-term weather variation on PCB movement through the environment. Specifically, it shows the consequences of the severe flooding, which occurred in early 2014 on sediment PCB concentrations in the River Thames.

Item Type:	Publication - Article
Digital Object Identifier (DOI):	10.1016/j.scitotenv.2016.03.029
UKCEH and CEH Sections/Science Areas:	Rees (from October 2014)
ISSN:	0048-9697
Additional Keywords:	PCBs, River Thames, INCA, sediment
NORA Subject Terms:	Hydrology
Date made live:	21 Apr 2016 10:10 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/513112

Item Type:

Publication - Article

Digital Object Identifier (DOI):

10.1016/j.scitotenv.2016.03.029

UKCEH and CEH Sections/Science Areas:

Rees (from October 2014)

ISSN:

0048-9697

Additional Keywords:

PCBs, River Thames, INCA, sediment

NORA Subject Terms:

Hydrology