Impact and recovery of pH in marine sediments subject to a temporary carbon dioxide leak

Taylor, Peter; Lichtschlag, Anna ORCID: https://orcid.org/0000-0001-8281-2165; Toberman, Matthew; Sayer, Martin D.J.; Reynolds, Andy; Sato, Toru; Stahl, Henrik. 2015 Impact and recovery of pH in marine sediments subject to a temporary carbon dioxide leak. International Journal of Greenhouse Gas Control, 38. 93-101. 10.1016/j.ijggc.2014.09.006

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Official URL: http://dx.doi.org/10.1016/j.ijggc.2014.09.006

Abstract/Summary

A possible effect of a carbon dioxide leak from an industrial sub-sea floor storage facility, utilised for Carbon Capture and Storage, is that escaping carbon dioxide gas will dissolve in sediment pore waters and reduce their pH. To quantify the scale and duration of such an impact, a novel, field scale experiment was conducted, whereby carbon dioxide gas was injected into unconsolidated sub-sea floor sediments for a sustained period of 37 days. During this time pore water pH in shallow sediment (5 mm depth) above the leak dropped >0.8 unit, relative to a reference zone that was unaffected by the carbon dioxide. After the gas release was stopped, the pore water pH returned to normal background values within a three-week recovery period. Further, the total mass of carbon dioxide dissolved within the sediment pore fluids above the release zone was modelled by the difference in DIC between the reference and release zones. Results showed that between 14 and 63% of the carbon dioxide released during the experiment could remain in the dissolved phase within the sediment pore water.

Item Type:	Publication - Article
Digital Object Identifier (DOI):	10.1016/j.ijggc.2014.09.006
ISSN:	17505836
Additional Keywords:	Carbon capture and storage; Sediment pore water; pH; CO2
Date made live:	16 Oct 2014 09:21 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/508625

Item Type:

Publication - Article

Digital Object Identifier (DOI):

10.1016/j.ijggc.2014.09.006

ISSN:

17505836

Additional Keywords:

Carbon capture and storage; Sediment pore water; pH; CO2

Date made live:

16 Oct 2014 09:21 +0 (UTC)

URI:

https://nora.nerc.ac.uk/id/eprint/508625