The atmospheric HCHO budget at Dumont d'Urville (East Antarctica): Contribution of photochemical gas-phase production versus snow emissions
Preunkert, Susanne; Legrand, Michel; Pépy, Guillaume; Gallée, Hubert; Jones, Anna ORCID: https://orcid.org/0000-0002-2040-4841; Jourdain, Bruno. 2013 The atmospheric HCHO budget at Dumont d'Urville (East Antarctica): Contribution of photochemical gas-phase production versus snow emissions. Journal of Geophysical Research: Atmospheres, 118 (23). 13,319-13,337. 10.1002/2013JD019864
Before downloading, please read NORA policies.Preview |
Text
© 2013. American Geophysical Union. All Rights Reserved. jgrd51007.pdf - Published Version Download (2MB) | Preview |
Abstract/Summary
HCHO was monitored throughout the year 2009 at the coastal East Antarctic site of Dumont d'Urville (DDU) using Aerolaser AL-4021 analyzers. The accurate determination of less than 100 pptv required optimization of the analyzers, in particular, to minimize effects of changing ambient temperatures. The impact of station activities and of the presence of large penguin colonies at the site in summer was scrutinized. The obtained contamination-free record indicates monthly means close to 50 pptv from May to September and a maximum of 200 pptv in January. Zero-dimensional and 2-D calculations suggest that in summer, the largest HCHO source is the gas-phase photochemistry (80%) mainly driven by methane oxidation, which is considerably greater than from snow emissions (20%). The influence of light alkenes, dimethyl sulfide, and halogens remains weak. In winter, snow emissions represent the main HCHO source (70%). These findings are compared to previous studies conducted at the West Antarctic coast. It is shown that in summer the HCHO production from methane chemistry is 3 times more efficient at DDU than at the west coast due to more frequent arrival of oxidant-rich air masses from inland Antarctica. Halogen chemistry is found to represent a weak HCHO sink at both West and East Antarctica. Compared to DDU, the shallower atmospheric boundary layer and the less efficient gas-phase production at the west coast make the snow pack the dominant HCHO source (85%) compared to gas-phase photochemistry (15%) there in summer.
Item Type: | Publication - Article |
---|---|
Digital Object Identifier (DOI): | 10.1002/2013JD019864 |
Programmes: | BAS Programmes > Polar Science for Planet Earth (2009 - ) > Chemistry and Past Climate |
ISSN: | 2169897X |
Additional Keywords: | atmospheric HCHO, coastal Antarctica, oxidative capacity |
Date made live: | 03 Mar 2014 09:27 +0 (UTC) |
URI: | https://nora.nerc.ac.uk/id/eprint/505096 |
Actions (login required)
View Item |
Document Downloads
Downloads for past 30 days
Downloads per month over past year