Dynamic modelling of the long term behaviour of cadmium, lead and mercury in Swiss forest soils using CHUM-AM

Rieder, Stephan R.; Tipping, Edward ORCID: https://orcid.org/0000-0001-6618-6512; Zimmermann, Stefan; Graf-Pannatier, Elisabeth; Waldner, Peter; Meili, Markus; Frey, Beat. 2014 Dynamic modelling of the long term behaviour of cadmium, lead and mercury in Swiss forest soils using CHUM-AM. Science of the Total Environment, 468-469. 864-876. 10.1016/j.scitotenv.2013.09.005

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Official URL: http://dx.doi.org/10.1016/j.scitotenv.2013.09.005

Abstract/Summary

The applicability of the dynamic soil model CHUM-AM was tested to simulate concentrations of Cd, Pb and Hg in five Swiss forest soils. Soil cores of up to 50 cm depth were sampled and separated into two defined soil layers. Soil leachateswere collected below the litter by zero-tension lysimeters and at 15 and 50 cm soil depths by tension lysimeters over two years. The concentrations of Cd, Pb and Hg in the solid phase and soil solution weremeasured by ICP-MS (Cd, Pb) or CV-AFS (Hg). Measured metal concentrations were compared with modelled concentrations using CHUM-AM. Additionally we ran the model with three different deposition scenarios (current deposition;maximumacceptable deposition according to the Swiss ordinance on Air Pollution Control; critical loads according to CLRTAP) to predict metal concentrations in the soils for the next 1000 years. Assuming current loads concentrations of Cd and Pb showed varying trends (increasing/decreasing) between the soils. Soils rich in organic carbon orwith a high pH value showed increasing trends in Cd and Pb concentrationswhereas the concentrations in the other soils decreased. In contrast Hg concentrations are predicted to further increase in all soils. Critical limits for Pb andHgwill partly be exceeded by current loads or by the critical loads proposed by the CLRTAP but the critical limits for Cd will rarely be reached within the next 1000 years. In contrast, maximal acceptable deposition will partly lead to concentrations above the critical limits for Pb in soils within the next 400 years, whereas the acceptable deposition of Cd will not lead to concentrations above the proposed critical limits. In conclusion the CHUM-AMmodel is able to accurately simulate heavymetal (Cd, Pb and Hg) concentrations in Swiss forest soils of various soil properties.

Item Type:	Publication - Article
Digital Object Identifier (DOI):	10.1016/j.scitotenv.2013.09.005
Programmes:	CEH Topics & Objectives 2009 - 2012 > Biogeochemistry > BGC Topic 2 - Biogeochemistry and Climate System Processes > BGC - 2.1 - Quantify & model processes that control the emission, fate and bioavailability of pollutants CEH Topics & Objectives 2009 - 2012 > Biogeochemistry > BGC Topic 3 - Managing Threats to Environment and Health > BGC - 3.1 - Develop temporally and spatially explicit risk assessment tools ...
UKCEH and CEH Sections/Science Areas:	Shore
ISSN:	0048-9697
Additional Keywords:	critical limits, critical loads, cadmium, lead, mercury, modelling soil concentrations
NORA Subject Terms:	Ecology and Environment Chemistry
Date made live:	03 Dec 2013 14:16 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/503368

Item Type:

Publication - Article

Digital Object Identifier (DOI):

10.1016/j.scitotenv.2013.09.005

Programmes:

CEH Topics & Objectives 2009 - 2012 > Biogeochemistry > BGC Topic 2 - Biogeochemistry and Climate System Processes > BGC - 2.1 - Quantify & model processes that control the emission, fate and bioavailability of pollutants
CEH Topics & Objectives 2009 - 2012 > Biogeochemistry > BGC Topic 3 - Managing Threats to Environment and Health > BGC - 3.1 - Develop temporally and spatially explicit risk assessment tools ...

UKCEH and CEH Sections/Science Areas:

Shore

ISSN:

0048-9697

Additional Keywords:

critical limits, critical loads, cadmium, lead, mercury, modelling soil concentrations