Bentonite reactivity in alkaline solutions: interim results of the Cyprus Natural Analogue Project (CNAP)
Alexander, W.R.; Milodowski, A.E.; Pitty, A.F.; Hardie, S.M.L.; Kemp, S.J. ORCID: https://orcid.org/0000-0002-4604-0927; Rushton, J.C. ORCID: https://orcid.org/0000-0001-5931-7537; Siathas, Andreas; Siathas, Avrim; MacKenzie, A.B.; Korkeakoski, P.; Norris, S.; Sellin, P.; Rigas, M.. 2013 Bentonite reactivity in alkaline solutions: interim results of the Cyprus Natural Analogue Project (CNAP). Clay Minerals, 48 (2). 235-249. 10.1180/claymin.2013.048.2.06
Before downloading, please read NORA policies.Preview |
Text
Alexander, Milodowski et al_2013_CNAP_Clay Minerals.pdf Download (2MB) | Preview |
Abstract/Summary
Bentonite is one of the more safety-critical components of the engineered barrier system in the disposal concepts developed for many types of radioactive waste. It is used due to its favourable properties (including plasticity, swelling capacity, colloid filtration, low hydraulic conductivity, high retardation of key radionuclides) and its stability in relevant geological environments. However, bentonite is unstable under alkaline conditions and this has driven interest in low-alkali cements (leachate pH of 10–11). To build a robust safety case, it is important to have supporting natural analogue data to confirm understanding of the likely long-term performance of bentonite. In Cyprus, the presence of natural bentonite in close proximity to natural alkaline groundwaters permits the zones of potential bentonite/alkaline water reaction to be studied as an analogy of the potential reaction zones in the repository. Here, the results indicate minimal volumetric reaction of bentonite, with production of a palygorskite secondary phase.
Item Type: | Publication - Article |
---|---|
Digital Object Identifier (DOI): | 10.1180/claymin.2013.048.2.06 |
ISSN: | 00098558 |
Additional Information. Not used in RCUK Gateway to Research.: | This article published Gold Open Access under a Creative Commons Attribution Licence |
Date made live: | 25 Jul 2013 14:07 +0 (UTC) |
URI: | https://nora.nerc.ac.uk/id/eprint/502754 |
Actions (login required)
View Item |
Document Downloads
Downloads for past 30 days
Downloads per month over past year