Segmented flow coil equilibrator coupled to a proton transfer reaction mass spectrometer for measurements of a broad range of volatile organic compounds in seawater

Wohl, Charel; Capelle, David; Jones, Anna ORCID: https://orcid.org/0000-0002-2040-4841; Sturges, William T.; Nightingale, Phillip D.; Else, Brent G.T.; Yang, Mingxi. 2019 Segmented flow coil equilibrator coupled to a proton transfer reaction mass spectrometer for measurements of a broad range of volatile organic compounds in seawater. Ocean Science, 15. 925-940. https://doi.org/10.5194/os-15-925-2019

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© Author(s) 2019. This work is distributed under the Creative Commons Attribution 4.0 License. This discussion paper is a preprint. It is a manuscript under review for the journal Ocean Science (OS).
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Official URL: https://www.ocean-sci.net/15/925/2019/os-15-925-20...

Abstract/Summary

We present a technique that utilises a segmented flow coil equilibrator coupled to a proton-transferreaction mass spectrometer to measure a broad range of dissolved volatile organic compounds. Thanks to its relatively large surface area for gas exchange, small internal volume, and smooth headspace–water separation, the equilibrator is highly efficient for gas exchange and has a fast response time (under 1 min). The system allows for both continuous and discrete measurements of volatile organic compounds in seawater due to its low sample water flow (100 cm3 min

Item Type:	Publication - Article
Digital Object Identifier (DOI):	https://doi.org/10.5194/os-15-925-2019
ISSN:	1812-0784
Date made live:	06 Mar 2019 12:09 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/522435

Item Type:

Publication - Article

Digital Object Identifier (DOI):

https://doi.org/10.5194/os-15-925-2019

ISSN:

1812-0784

Date made live:

06 Mar 2019 12:09 +0 (UTC)

URI:

https://nora.nerc.ac.uk/id/eprint/522435