Transferability of a Bayesian belief network across diverse agricultural catchments using high-frequency hydrochemistry and land management data

Negri, Camilla; Schurch, Nicholas; Wade, Andrew J.; Mellander, Per-Erik; Stutter, Marc; Bowes, Micheal J. ORCID: https://orcid.org/0000-0002-0673-1934; Mzyece, Chisha Chongo; Glendell, Miriam. 2024 Transferability of a Bayesian belief network across diverse agricultural catchments using high-frequency hydrochemistry and land management data. Science of The Total Environment, 174926. https://doi.org/10.1016/j.scitotenv.2024.174926

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Abstract/Summary

Biogeochemical catchment models are often developed for a single catchment and, as a result, often generalize poorly beyond this. Evaluating their transferability is an important step in improving their predictive power and application range. We assess the transferability of a recently developed Bayesian Belief Network (BBN) that simulated monthly stream phosphorus (P) concentrations in a poorly-drained grassland catchment through application to three further catchments with different hydrological regimes and agricultural land uses. In all catchments, flow and turbidity were measured sub-hourly from 2009 to 2016 and supplemented with 400–500 soil P test measurements. In addition to a previously parameterized BBN, five further model structures were implemented to incorporate in a stepwise way: in-stream P removal using expert elicitation, additional groundwater P stores and delivery, and the presence or absence of septic tank treatment, and, in one case, Sewage Treatment Works. Model performance was tested through comparison of predicted and observed total reactive P (TRP) concentrations and percentage bias (PBIAS). The original BBN accurately simulated the absolute values of observed flow and TRP concentrations in the poorly and moderately drained catchments (albeit with poor apparent percentage bias scores; 76 % ≤ PBIAS≤94 %) irrespective of the dominant land use, but performed less well in the groundwater-dominated catchments. However, including groundwater total dissolved P (TDP) and Sewage Treatment Works (STWs) inputs, and in-stream P uptake improved model performance (−5 % ≤ PBIAS≤18 %). A sensitivity analysis identified redundant variables further helping to streamline the model applications. An enhanced BBN model capable for wider application and generalisation resulted.

Item Type:	Publication - Article
Digital Object Identifier (DOI):	https://doi.org/10.1016/j.scitotenv.2024.174926
UKCEH and CEH Sections/Science Areas:	Water Resources (Science Area 2017-)
ISSN:	0048-9697
Additional Information. Not used in RCUK Gateway to Research.:	Open Access paper - full text available via Official URL link.
Additional Keywords:	hybrid network, expert elicitation, model universality, sensitivity analysis, phosphorus, structural uncertainty
NORA Subject Terms:	Hydrology Mathematics Data and Information
Related URLs:	Other
Date made live:	25 Jul 2024 08:18 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/537768

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