Origins of the seasonal variability of PM2.5 sources in a rural site in northern France

Espina Martin, P. ORCID: https://orcid.org/0000-0001-7995-1033; Perdrix, E.; Alleman, L.Y.; Coddeville, P.. 2024 Origins of the seasonal variability of PM2.5 sources in a rural site in northern France. Atmospheric Environment, 333, 120660. 16, pp. https://doi.org/10.1016/j.atmosenv.2024.120660

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Abstract/Summary

Air quality in rural areas results from the crossing of aged air masses transported from urban areas with local emissions dominated by agriculture and vegetation. The result is a complex mixture of primary and secondary atmospheric species, coming from varied sources and geographical areas. We implemented a methodology for deconvoluting and determining the geographical origins of the main aerosol sources impacting a typical rural area of northern France. A one-year field campaign was conducted in a rural site located between Paris and Brussels from 03/2018 to 02/2019. Hourly-based observations of inorganic and organic precursor gases and PM2.5 speciation were collected using on-line instrumentation. The annual PM2.5 concentrations of 12.2 ± 9.23 μg m-3 were explained by four sources extracted through positive matrix factorization analyses: combustion (40.2%), NO3-rich (26.8%), SO4-rich (18%) and mixed aged marine (15%). The combustion and SIA-rich sources drive 85 % of the yearly PM2.5 mass and variability. The combustion factor was most prominent during winter (53.3% of PM2.5 mass) due to high contributions from local and regional transport of biomass burning pollutants (winter OC/EC = 6.0; OC-to-OM factor = 2.05). In summer, it was most likely driven by secondary organic aerosol production and agricultural waste burning events (summer OC/EC = 8.6; OC-to-OM factor= 1.85). Comparing with other regional sites, we observed a strong regional background of carbonaceous particles regardless of the site typology. The SIA fraction is dominated by the NO3-rich source compared to the SO4-rich source. In spring, NO3-rich particles dominate PM2.5 (36.9%) due to intense agricultural activity. The temporal variability is driven by transport processes from the Benelux area in a North-to-South gradient of decreasing concentrations. A minor proportion of the NH4NO3 observed seems to be due to the local effects of morning dew and photochemical oxidation of NO2 in the afternoon. HNO3 appears to be the limiting factor for local NH4NO3 formation. PM2.5 toxicity in rural areas with low population densities should be not only addressed based on mass concentration, but also considering the chemical composition of particles as people from rural environments are exposed to high contributions from biomass burning sources and secondary inorganic aerosols triggered by the NH3 excess.

Item Type:	Publication - Article
Digital Object Identifier (DOI):	https://doi.org/10.1016/j.atmosenv.2024.120660
UKCEH and CEH Sections/Science Areas:	Atmospheric Chemistry and Effects (Science Area 2017-)
ISSN:	1352-2310
Additional Information. Not used in RCUK Gateway to Research.:	Open Access paper - full text available via Official URL link.
Additional Keywords:	PM2.5, pollution sources, positive matrix factorization, monitor for aerosols and gases in ambient air (MARGA), inorganic precursor gases, secondary inorganic aerosols (SIA), air quality
NORA Subject Terms:	Atmospheric Sciences
Date made live:	17 Jun 2024 15:20 +0 (UTC)
URI:	https://nora.nerc.ac.uk/id/eprint/537591

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