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A year-long record of size-segregated aerosol composition at Halley, Antarctica

Rankin, Andrew M.; Wolff, Eric W.. 2003 A year-long record of size-segregated aerosol composition at Halley, Antarctica. Journal of Geophysical Research, 108 (D24), 4775. 12, pp. 10.1029/2003JD003993

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Abstract/Summary

Size-segregated aerosol samples were collected with a cascade impactor at 2 week intervals for a year at the research station Halley, situated near the coast in the Weddell Sea region of Antarctica. Sea salt is a major component of aerosol throughout the year, and we estimate that at least 60% of the total sea salt arriving at Halley is from brine and frost flowers on the sea ice surface rather than open water. Chloride in sea-salt particles is depleted relative to sodium in summer, consistent with loss of HCl as sea-salt particles react with gaseous acidic species, but is enhanced in large particles in winter because of fractionation occurring during the production of new sea ice. Non-sea-salt sulphate peaks in the summer, with the majority being in small particles indicative of a gas phase origin. The distribution of methane sulphonic acid closely follows that of non-sea-salt sulphate. In the winter, non-sea-salt sulphate is frequently negative, especially on stages collecting large particle sizes, consistent with the source of sea salt during the winter being predominantly the sea ice surface rather than open water. Nitrate peaks in the spring and summer and shows some association with sea-salt particles.

Item Type: Publication - Article
Digital Object Identifier (DOI): 10.1029/2003JD003993
Programmes: BAS Programmes > Antarctic Science in the Global Context (2000-2005) > Signals in Antarctica of Past Global Changes
ISSN: 0148-0227
Additional Keywords: aerosol, cascade impactor, Antarctica
NORA Subject Terms: Atmospheric Sciences
Chemistry
Date made live: 13 Feb 2012 10:03
URI: http://nora.nerc.ac.uk/id/eprint/12948

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