Modelling multi-phase halogen chemistry in the coastal marine boundary layer: investigation of the relative importance of local chemistry vs. long-range transport
Lowe, D.; Ryder, J.; Leigh, R.; Dorsey, J.R.; McFiggans, G.. 2010 Modelling multi-phase halogen chemistry in the coastal marine boundary layer: investigation of the relative importance of local chemistry vs. long-range transport. Atmospheric Chemistry and Physics Discussions, 10. 19429-19467. 10.5194/acpd-10-19429-2010Full text not available from this repository.
Measurements of significant concentrations of IO, I2 and BrO in a semi-polluted coast environment at Roscoff, in North-West France, have been made as part of the Reactive Halogens in the Marine Boundary Layer (RHaMBLe) campaign undertaken in September 2006. We use a one-dimensional column model, with idealised I2 emissions predicted using macroalgael maps and tidal data from the littoral area surrounding Roscoff, to investigate the probable causes for these observations. The coupled microphysical and chemical aerosol model simulates mixed-phase halogen chemistry using two separate particle modes, seasalt and non-seasalt, each comprising of eight size-sections. This work confirms the finding of a previous study that the BrO measurements are most likely caused by unknown, local sources. We find that the remote observations of IO and I2 are best replicated using the I2 recycling mechanism suggested by previous studies, but that such a mechanism is not wholly necessary. However we suggest that focussed observations of the changes in NOx and NOy concentrations, as well as changes in the nitrate fraction of the non-seasalt aerosol mode, in the presence of I2 bursts could be used to determine the atmospheric relevance of the predicted I2 recycling mechanism.
|Item Type:||Publication - Article|
|Digital Object Identifier (DOI):||10.5194/acpd-10-19429-2010|
|Programmes:||CEH Topics & Objectives 2009 - 2012 > Biogeochemistry > BGC Topic 2 - Biogeochemistry and Climate System Processes > BGC - 2.1 - Quantify & model processes that control the emission, fate and bioavailability of pollutants|
|CEH Sections:||Billett (to November 2013)|
|Additional Information. Not used in RCUK Gateway to Research.:||Atmospheric Chemistry and Physics Discussions is an Open Access journal - to access full text, please click on OFFICIAL URL link|
|NORA Subject Terms:||Atmospheric Sciences|
|Date made live:||16 Dec 2010 13:09|
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